SMIRKS
[C:1]([S:2][C:3]([C:4]([C:5](=[O:6])[C:7](=[O:8])[O:9][H:21])([H:22])[H:23])([H:24])[H:25])([H:26])([H:27])[H:28].[H][C@:11]([N:10]([H:36])[H:37])([C:12]([C:13]1:[C:14]([H:29]):[N:15]:[C:16]([H:30]):[N:17]:1[H:31])([H:32])[H:33])[C:18](=[O:19])[O:20][H:34]>>[H][C@:5]([C:4]([C:3]([S:2][C:1]([H:26])([H:27])[H:28])([H:24])[H:25])([H:22])[H:23])([C:7](=[O:8])[O:9][H:21])[N:10]([H:36])[H:37].[O:6]=[C:11]([C:12]([C:13]1:[C:14]([H:29]):[N:15]:[C:16]([H:30]):[N:17]:1[H:31])([H:32])[H:33])[C:18](=[O:19])[O:20][H:34]
Source Database Data
| Rxn Index | Original Reaction Text | Natural | Organism | Protein Refs | Protein DB | EC Number |
|---|---|---|---|---|---|---|
| 153064 | L-histidine + 4-(methylsulfanyl)-2-oxobutanoate = 3-((1H-imidazo)-4-yl)-2-oxopropanoate + L-methionine | False | Solanum lycopersicum | nan | 2.6.1.117 |
Derived Partial Reactions
EVODEX.1-P2846
![[H][C@:11]([N:10]([H:36])[H:37])([C:12]([C:13]1:[C:14]([H:29]):[N:15]:[C:16]([H:30]):[N:17]:1[H:31])([H:32])[H:33])[C:18](=[O:19])[O:20][H:34]>>[H]OC(=O)[C@]([H])(C([H])([H])C([H])([H])SC([H])([H])[H])[N:10]([H:36])[H:37].O=[C:11]([C:12]([C:13]1:[C:14]([H:29]):[N:15]:[C:16]([H:30]):[N:17]:1[H:31])([H:32])[H:33])[C:18](=[O:19])[O:20][H:34]](../images/EVODEX.1-P2846.svg)
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EVODEX.1-P2847
[C:7](=[O:8])[O:9][H:21])([H:22])[H:23])([H:24])[H:25])([H:26])([H:27])[H:28]>>[H]N([H])[C@@:5]([H])([C:4]([C:3]([S:2][C:1]([H:26])([H:27])[H:28])([H:24])[H:25])([H:22])[H:23])[C:7](=[O:8])[O:9][H:21].[H]OC(=O)C(C([H])([H])C1:C([H]):N:C([H]):N:1[H])=[O:6]](../images/EVODEX.1-P2847.svg)
[C:1]([S:2][C:3]([C:4]([C:5](=[O:6])[C:7](=[O:8])[O:9][H:21])([H:22])[H:23])([H:24])[H:25])([H:26])([H:27])[H:28]>>[H]N([H])[C@@:5]([H])([C:4]([C:3]([S:2][C:1]([H:26])([H:27])[H:28])([H:24])[H:25])([H:22])[H:23])[C:7](=[O:8])[O:9][H:21].[H]OC(=O)C(C([H])([H])C1:C([H]):N:C([H]):N:1[H])=[O:6]