SMIRKS
[H][C:10]([C:11]1([C:12]([H:36])([H:37])[H:38])[S:13][C@:14]2([H:39])[C@@:15]([N:16]([C:17](=[O:18])[C@:19]([N:20]([H:40])[H:41])([C:21]3:[C:22]([H:42]):[C:23]([H:43]):[C:24]([H:44]):[C:25]([H:45]):[C:26]:3[H:46])[H:47])[H:48])([H:49])[C:27](=[O:28])[N:29]2[C@@:30]1([H])[C:31](=[O:32])[O:33][H:50])([H:52])[H:53].[H][O:9][C:7]([C:5]([C:4]([C:2]([C:1]([H:62])([H:63])[H:64])([C:3]([H:55])([H:56])[H:57])[H:61])([H:59])[H:60])=[O:6])=[O:8].[O:34]=[O:35]>>[C:7](=[O:8])=[O:9].[C:10]1([H:52])([H:53])[C:11]([C:12]([H:36])([H:37])[H:38])=[C:30]([C:31](=[O:32])[O:33][H:50])[N:29]2[C@:14]([H:39])([S:13]1)[C@@:15]([N:16]([C:17](=[O:18])[C@:19]([N:20]([H:40])[H:41])([C:21]1:[C:22]([H:42]):[C:23]([H:43]):[C:24]([H:44]):[C:25]([H:45]):[C:26]:1[H:46])[H:47])[H:48])([H:49])[C:27]2=[O:28].[H][O:34][C:5]([C:4]([C:2]([C:1]([H:62])([H:63])[H:64])([C:3]([H:55])([H:56])[H:57])[H:61])([H:59])[H:60])=[O:6].[H][O:35][H]
Source Database Data
| Rxn Index | Original Reaction Text | Natural | Organism | Protein Refs | Protein DB | EC Number |
|---|---|---|---|---|---|---|
| 57459 | ampicillin + 2-oxo-4-methylpentanoate + O2 = cephalexin + succinate + CO2 + H2O | False | Streptomyces clavuligerus | nan | 1.14.20.1 |
Derived Partial Reactions
EVODEX.1-P627
![[H][C:10]([C:11]1([C:12]([H:36])([H:37])[H:38])[S:13][C@:14]2([H:39])[C@@:15]([N:16]([C:17](=[O:18])[C@:19]([N:20]([H:40])[H:41])([C:21]3:[C:22]([H:42]):[C:23]([H:43]):[C:24]([H:44]):[C:25]([H:45]):[C:26]:3[H:46])[H:47])[H:48])([H:49])[C:27](=[O:28])[N:29]2[C@@:30]1([H])[C:31](=[O:32])[O:33][H:50])([H:52])[H:53].[H][O:9][C:7]([C:5]([C:4]([C:2]([C:1]([H:62])([H:63])[H:64])([C:3]([H:55])([H:56])[H:57])[H:61])([H:59])[H:60])=[O:6])=[O:8].O=[O:34]>>[C:7](=[O:8])=[O:9].[C:10]1([H:52])([H:53])[C:11]([C:12]([H:36])([H:37])[H:38])=[C:30]([C:31](=[O:32])[O:33][H:50])[N:29]2[C@:14]([H:39])([S:13]1)[C@@:15]([N:16]([C:17](=[O:18])[C@:19]([N:20]([H:40])[H:41])([C:21]1:[C:22]([H:42]):[C:23]([H:43]):[C:24]([H:44]):[C:25]([H:45]):[C:26]:1[H:46])[H:47])[H:48])([H:49])[C:27]2=[O:28].[H][O:34][C:5]([C:4]([C:2]([C:1]([H:62])([H:63])[H:64])([C:3]([H:55])([H:56])[H:57])[H:61])([H:59])[H:60])=[O:6]](../images/EVODEX.1-P627.svg)
[H][C:10]([C:11]1([C:12]([H:36])([H:37])[H:38])[S:13][C@:14]2([H:39])[C@@:15]([N:16]([C:17](=[O:18])[C@:19]([N:20]([H:40])[H:41])([C:21]3:[C:22]([H:42]):[C:23]([H:43]):[C:24]([H:44]):[C:25]([H:45]):[C:26]:3[H:46])[H:47])[H:48])([H:49])[C:27](=[O:28])[N:29]2[C@@:30]1([H])[C:31](=[O:32])[O:33][H:50])([H:52])[H:53].[H][O:9][C:7]([C:5]([C:4]([C:2]([C:1]([H:62])([H:63])[H:64])([C:3]([H:55])([H:56])[H:57])[H:61])([H:59])[H:60])=[O:6])=[O:8].O=[O:34]>>[C:7](=[O:8])=[O:9].[C:10]1([H:52])([H:53])[C:11]([C:12]([H:36])([H:37])[H:38])=[C:30]([C:31](=[O:32])[O:33][H:50])[N:29]2[C@:14]([H:39])([S:13]1)[C@@:15]([N:16]([C:17](=[O:18])[C@:19]([N:20]([H:40])[H:41])([C:21]1:[C:22]([H:42]):[C:23]([H:43]):[C:24]([H:44]):[C:25]([H:45]):[C:26]:1[H:46])[H:47])[H:48])([H:49])[C:27]2=[O:28].[H][O:34][C:5]([C:4]([C:2]([C:1]([H:62])([H:63])[H:64])([C:3]([H:55])([H:56])[H:57])[H:61])([H:59])[H:60])=[O:6]