SMIRKS
[H][C:4]([C:2]([C:1]([H:18])([H:19])[H:20])=[O:3])([O:5][H:15])[H:16].[C:6]([C:7]1:[C:8]([H:21]):[C:9]([H:22]):[C:10]([C:11](=[O:12])[H:23]):[C:13]([H:24]):[C:14]:1[H:25])([H:26])([H:27])[H:28]>>[H][O:12][C@:11]([C@:4]([C:2]([C:1]([H:18])([H:19])[H:20])=[O:3])([O:5][H:15])[H:16])([C:10]1:[C:9]([H:22]):[C:8]([H:21]):[C:7]([C:6]([H:26])([H:27])[H:28]):[C:14]([H:25]):[C:13]:1[H:24])[H:23]
Source Database Data
| Rxn Index | Original Reaction Text | Natural | Organism | Protein Refs | Protein DB | EC Number |
|---|---|---|---|---|---|---|
| 249359 | 4-methylbenzaldehyde + 1-hydroxypropan-2-one = (3R,4S)-3,4-dihydroxy-4-(4-methylphenyl)butan-2-one | False | Sus scrofa | nan | 3.4.23.1 |
Derived Partial Reactions
EVODEX.1-P5286
![[H][C:4]([C:2]([C:1]([H:18])([H:19])[H:20])=[O:3])([O:5][H:15])[H:16].[C:6]([C:7]1:[C:8]([H:21]):[C:9]([H:22]):[C:10]([C:11](=[O:12])[H:23]):[C:13]([H:24]):[C:14]:1[H:25])([H:26])([H:27])[H:28]>>[H][O:12][C@:11]([C@:4]([C:2]([C:1]([H:18])([H:19])[H:20])=[O:3])([O:5][H:15])[H:16])([C:10]1:[C:9]([H:22]):[C:8]([H:21]):[C:7]([C:6]([H:26])([H:27])[H:28]):[C:14]([H:25]):[C:13]:1[H:24])[H:23]](../images/EVODEX.1-P5286.svg)
[H][C:4]([C:2]([C:1]([H:18])([H:19])[H:20])=[O:3])([O:5][H:15])[H:16].[C:6]([C:7]1:[C:8]([H:21]):[C:9]([H:22]):[C:10]([C:11](=[O:12])[H:23]):[C:13]([H:24]):[C:14]:1[H:25])([H:26])([H:27])[H:28]>>[H][O:12][C@:11]([C@:4]([C:2]([C:1]([H:18])([H:19])[H:20])=[O:3])([O:5][H:15])[H:16])([C:10]1:[C:9]([H:22]):[C:8]([H:21]):[C:7]([C:6]([H:26])([H:27])[H:28]):[C:14]([H:25]):[C:13]:1[H:24])[H:23]
EVODEX.1-P5287
:[C:9]([H:22]):[C:10]([C:11](=[O:12])[H:23]):[C:13]([H:24]):[C:14]:1[H:25])([H:26])([H:27])[H:28]>>[H]O[C@@]([H])(C(=O)C([H])([H])[H])[C@:11]([C:10]1:[C:9]([H:22]):[C:8]([H:21]):[C:7]([C:6]([H:26])([H:27])[H:28]):[C:14]([H:25]):[C:13]:1[H:24])([O:12][H])[H:23]](../images/EVODEX.1-P5287.svg)
[C:6]([C:7]1:[C:8]([H:21]):[C:9]([H:22]):[C:10]([C:11](=[O:12])[H:23]):[C:13]([H:24]):[C:14]:1[H:25])([H:26])([H:27])[H:28]>>[H]O[C@@]([H])(C(=O)C([H])([H])[H])[C@:11]([C:10]1:[C:9]([H:22]):[C:8]([H:21]):[C:7]([C:6]([H:26])([H:27])[H:28]):[C:14]([H:25]):[C:13]:1[H:24])([O:12][H])[H:23]